One of the most exciting possibilities enabled by transiting exoplanets is to measure their atmospheric properties through the technique of transmission spectroscopy: the variation of the transit depth as a function of wavelength due to starlight interacting with the atmosphere of the exoplanet. Motivated by the need of optical transmission spectra of exoplanets, we recently launched the Arizona-CfA-Católica Exoplanet Spectroscopy Survey (ACCESS), which aims at studying the atmospheres of ~20 exoplanets ranging from super-Earths to hot-Jupiters in the entire optical atmospheric window using ground-based facilities. In this talk, I will present the survey, the astrostatistical challenges it poses and first results.