ISO has shown the need to obtain a reliable calibration network of good pedigree to permit data from a wide range of instruments, covering an enormous wavelength range, to be calibrated on a consistent scale. We describe the first results of a programme to extend the Landolt calibration standards to at least V=19. At the same time we calibrate into the near-infrared JHK bands and measure fields separated from the celestial equator. This programme is one of several coordinated efforts to find faint type AV and KIII stars suitable for the mid-IR calibration of the Spanish 10-m Gran Telescopio Canarias (GTC). We have obtained a total of 34 712 measurements of 373 stars in 26 quasar fields between Declination -30o and +70o, calculating magnitudes with high precision in the visible and near-infrared (UBVRIJHK). We describe the results obtained and the characteristics of the sample of stars. The typical error on the magnitude in a single band is <1%, including all error sources. Very few candidate type AV or KIII stars are found, either in our sample, or amongst the fainter Landolt stars. We conclude that both samples are increasingly dominated by local dwarfs at increasingly faint magnitudes. We discuss the implications for taking mid-infrared calibration to the increasingly faint limits required by post-ISO instrumentation. The next steps in this project will be: -- To increase significantly the number of fields covered to ˜40. -- To take additional observations of all poorly covered fields and to add JHK data where none is available. -- To use our existing database to extend Landolt photometry of Selected Areas to include many stars not previously measured. -- To assign a spectral type to all candidate KIII and AV stars in our sample.