Bibcode
Iglesias-Groth, S.; García-Hernández, D. A.; Cataldo, Franco; Manchado, A.
Referencia bibliográfica
Monthly Notices of the Royal Astronomical Society, Volume 423, Issue 3, pp. 2868-2878.
Fecha de publicación:
7
2012
Número de citas
30
Número de citas referidas
25
Descripción
The infrared spectra, as well as the integrated molar absorptivity
(Ψ) and the molar extinction coefficient (ɛ) of each
infrared transition of the hydrogenated fullerenes (known as fulleranes)
C60H36, C60H18 and
C70H38, and a mixture of fulleranes generally
referred to as 77 per cent of C60Hx and 22 per
cent C70Hy with x≈y > 30, are presented and
discussed. These data are useful for the search, identification and
quantitative determination of fulleranes in space after the recent
discovery that their parent molecules, C60 and
C70, are more abundant in space than initially thought, being
present in a variety of H-rich circumstellar environments such as
planetary nebulae and only mild H-deficient R Coronae Borealis stars,
and in the interstellar medium. It is shown that the C-H stretching band
of the fulleranes C60H36,
C60H18 and C70H38, and their
mixture may be most useful for the identification of these molecules
because their Ψ and ɛ values are unique in terms of
strength, overcoming by far the typical Ψ and ɛ values of
reference molecules such as adamantane and docosane, as well as typical
ɛ literature data for aliphatic molecules. In contrast to the
rather simple infrared spectra of C60H36 and
C60H38, the infrared spectra of two
C60H18 isomers are reported as characterized by a
rich number of bands which may allow an easier identification than the
higher homologues. The dependence of the infrared bands of fulleranes on
temperature was studied over a wide range of temperatures (from
-180°C to +250°C) and extrapolated to 0 K.
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