Bibcode
Martinez, R. A.; Karma, A.; Flemings, M. C.
Referencia bibliográfica
eprint arXiv:cond-mat/0607148
Fecha de publicación:
7
2006
Número de citas
0
Número de citas referidas
0
Descripción
A model for diffusion-controlled spherical particle growth is presented
and solved numerically, showing how, on cooling at sufficient rate from
a given fraction solid, growth velocity first increases, and then
decreases rapidly when solute fields of adjacent particles overlap. An
approximate analytical solution for the spherical particle growth
velocity is then developed and shown to be valid until the solute fields
begin to overlap. A particle stability model is next presented, building
on the above analytic solution. This model permits prediction of the
maximum cooling rate at which a semi-solid slurry or reheated semi-solid
billet can be cooled while still retaining the spherical growth
morphology. The model shows that particle stability is favored by high
particle density, high fraction solid and low cooling rate. The
predictions of the stability model are found to be in good quantitative
agreement with experimental data collected for Al-4.5wt%Cu alloy.
Engineering applications of the results obtained are discussed.